Thicke will perform a new single at the June show
Kevin Hart and Tracy Morgan are also set to appear at the event on June 29
The comedian is unveiled as awards show emcee during Wednesday's "106 & Park"
"Kevin Hart: Let Me Explain" will duke it out with "12 Years a Slave" for Best Movie
The 33-year-old cable channel just celebrated its 7th and 13th best week's ever, back-to-back
The show's 7.6 million total viewers ranked only second to 2009's Michael Jackson tribute
The pop star sang her new song perhaps a little too perfectly at Sunday's awards show for some viewers
Drake led with the most nominations at the awards show on Sunday from L.A.'s Nokia Theatre
Only the Super Bowl and the Grammys drove social chatter more than the BET Awards in 2012
Smiles? Posing for photos? Penn lightens pre-Fourth party fireworks spread from Malibu to the Hollywood hills
D'Angelo performs "Untitled (How Does It Feel)" and new song, "Sugar Daddy"
"Avengers" star Samuel L. Jackson to preside over this year's BET Awards; Chris Brown and Nicki Minaj to perform
Chris Brown wins viewers choice award - no, Rihanna. No wait: Chris Brown.
The funnyman also stars in Fox's upcoming sitcom "Little in Common"
10th annual awards include performances by Chris Brown, Kanye West
Queen Latifah hosts BET Awards, James Franco returns to "General Hospital," MTV reruns "Jersey Shore," Spike adds originals and salutes "Star Wars"