The former secretary of state will make a guest appearance on the NBC sitcom, a spokesperson for Rice confirmed to TheWrap.
She taped her appearance on the show last month.
According to Politico, Tina Fey said on her book tour that Rice will play Alec Baldwin's girlfriend. As fans of "30 Rock" remember, Baldwin's Jack Donaghy previously worked in the Bush Administration during a low point in his career at the network.
Now if they could only get Henry Kissinger to play an NBC page.